Materials Science and Engineering (Joint PhD)

Research Interests: Interaction of light with matter, physics of nanostructures and interfaces, metamaterials, material science, plasmonics, and surfactants, semiconductor photonics and electronics, epitaxial crystal growth, materials and devices for energy and infrared applications.

Research Interests: Scientific computing and numerical analysis: Efficient computational methods for complex fluids, plasma physics, electromagnetism and other physical applications.

Research Interests: membranes, polymer science, material science, separations, surface chemistry

Research Interests: Condensed Matter Physics, Soft materials, Colloids, Liquid Crystals, Computational Physics, Physics Education Soft matter physics is the study of matter that is all around us in everyday life: soaps, oil, foods, sand, foams, and biological matter. All of these are readily deformable at room temperature and combine properties of both fluids and solids. Despite their ubiquity, these materials are extremely complicated. Unlike simple fluids like water, they have rich internal structure; unlike crystalline solids they are typically not periodically ordered. Moreover, they exist in long-lived metastable states far from equilibrium and respond to stimuli such as applied electric and magnetic fields, temperature and pressure. My work seeks to understand how these materials respond to shape: how they self-organize on curved surfaces or in complex geometries and how this knowledge can be used both to sculpt desirable shapes at the microscopic scale and create shape changing systems like soft robots. We use high performance computing to simulate and predict these behaviors and work closely with experimentalists at Tufts and beyond.

Research Interests: Condensed Matter Physics

Research Interests: sustainable energy, superconducting materials, materials science

Research Interests: I am interested in synthesis and characterization in inorganic and materials chemistry. I am especially interested in fundamental chemistry that has important societal implications. My research laboratory currently works in several areas: Earth-abundant molecular light absorbers and emitters. Molecular light absorbers and emitters are used in photoredox catalysis, dye-sensitized solar cells, and organic light-emitting diodes (OLEDs). We are exploring high-spin complexes of iron and manganese to prepare new molecules that absorb and emit light. Volatile molecules carrying metal-atom equivalents for superconducting wires. Cryogenic superconducting wires enable quantum bits based on Josephson junctions. We are developing new molecules and methods to deposit the electropositive metals that make up these wires from chemical vapors. Thin-film photovoltaics with earth-abundant, sulfide-based absorber layers. Thin-film photovoltaics (solar cells) provide electricity from sunlight with just a few hundred nm of light-absorbing material. We are exploring binary and ternary sulfides as new sources of earth-abundant photovoltaics. I am developing new research programs in several areas: Zero-emissions ironmaking. The synthesis of iron metal from iron ore contributes ca. 4% of global carbon dioxide emissions. I am interested in alternative thermochemical methods of making iron from iron oxides. New superconducting materials. Near-room-temperature superconductors have recently been realized in compressed hydrides. I am interested in new hydride compounds that are stable at ambient pressure and might serve as ambient-pressure, ambient-temperature superconductors.

Research Interests: thermophotovoltaics, optoelectronics, energy harvesting, nanofabrication

Research Interests: Clean energy, fuels and chemicals, experimental and computational catalysis

Research Interests: Mathematical models of material behavior; Nonlinear magneto- and electromechanical interactions; Biomechanics of soft materials; Rubber elasticity and inelasticity

Research Interests: Sustainability, experimental heterogeneous catalysis, clean energy, fuels and chemicals, biomass

Research Interests: Biomedical optics, diffuse optical imaging, functional near-infrared spectroscopy, quantitative tissue oximetry.

Research Interests: label-free high resolution tissue imaging, non-linear microscopy, metabolic imaging, matrix characterization, in vivo flow cytometry, cancer detection, osteoarthritis, neurodegenerative diseases

Research Interests: geotechnical, laboratory testing, automation, soil behavior, physical properties, mechanical properties, material science

Research Interests: heat transfer, apparent slip, thermal management of electronics, mass transfer in supercritical fluids and thermoelectricity, material science

Research Interests: Scientific computing and numerical analysis; Parallel multigrid and multilevel methods for large-scale coupled systems; Efficient numerical methods for reservoir simulation, fluid-structure interaction, and other applications.

Research Interests: Mechanics of materials; effective properties of heterogeneous materials; microstructure-property relationships; applications to material science

Research Interests: biopolymer engineering, biomaterials, material science, tissue engineering, bioengineering, cellular agriculture

Research Interests: Bioorganic Chemistry and Chemical Biology The research interests of the Kumar laboratory are centered on the (1) use of chemistry to design molecules to interrogate and illuminate fundamental mechanisms in biology, or be used as therapeutics; and (2) use of biology to "evolve" and "select" molecules that can perform chemistry in non-biological and medicinal settings. These are some questions we are trying to answer: (i) Is it possible to design and mimic natural proteins and other biological macromolecules by use of building blocks that nature does not use – and whether such constructs can be endowed with properties that are not found in biology?; (ii) How did the first enzymes arise in the imagined Darwin's pond – is there a way to recreate this scenario and in the process develop a fundamentally new method to create enzymes?; (iii) Biology uses phase separation, that is, clustering of different compounds in confined locations – a process that is key in orchestrating the daily activities of a cell – can we find methods that can predictably dictate where molecules are located in a given environment and thereby direct the phenotype that is generated?; (iv) Can we rationally design small molecules and peptides that can function against antibiotic resistant bacteria that are threatening the most basic tenet of modern medicine?

Research Interests: metabolic engineering, tissue engineering, systems biology

Research Interests: Theoretical and Computational Biophysical Chemistry. The YSL Group aims to elucidate the structures and functions of biomolecules by integrating the power of advanced computations with the elegance of chemical theory. Our focus is to develop and apply computational methodology to significant biological problems that are difficult to address experimentally. Two major research projects in the YSL Group are (1) to understand and design cyclic peptides with desired conformations to modulate protein–protein interactions and (2) to elucidate the structural and functional roles of post-translational modifications and non-natural amino acids on protein folding.

Research Interests: Quantum Information, Quantum Simulation, Adiabatic Quantum Computation, Computational Physics Quantum information faces three basic questions. Firstly, what are quantum computers good for? Secondly, how do we build one? Thirdly, what will quantum information contribute if technological obstacles to constructing a large scale quantum computer prove insuperable? The first question is the search for problems which quantum computers can solve more easily than classical computers. The second is an investigation of which physical systems one could use to build a quantum computer. The third leads to the search for spinoffs in classical computation, and the question of where the classical/quantum boundary lies. I am interested in all three questions.

Research Interests: Bioanalytical and Materials Chemistry. The Mace group applies a multidisciplinary approach—combining aspects of chemistry, materials science, biophysics, and engineering—to study the properties of interfaces, develop new materials, and solve outstanding problems in global health. Immiscible Systems. When mixed, many solutions of polymers, surfactants, and salts form immiscible phases. We are interested in characterizing the properties of the interfaces between immiscible liquid phases and applying immiscible systems to the study of complex mixtures. We are particularly interested in those immiscible systems that share water as a common solvent. Paper Diagnostics. Successful implementation of point-of-care diagnostics has the potential to affect the global management of diseases. Paper is an attractive platform with which to develop assays designed specifically for the developing world because the infrastructure required to develop them is minimal and the materials needed to manufacture them are inexpensive. We will develop new materials that can enable biochemical assays that are not currently possible using paper alone.

Research Interests: solidification processes, thermal manufacturing, machine design, materials science

Research Interests: Signal and image processing, tomographic image formation and object characterization, inverse problems, regularization, statistical signal and imaging processing, and computational physical modeling. Applications explored include medical imaging and image analysis, environmental monitoring and remediation, landmine and unexploded ordnance remediation, and automatic target detection and classification.

Research Interests: nanophotonics, optical beam shaping, neuroengineering, chip-scale imaging and microscopy, quantum information systems Research Website: https://sites.tufts.edu/amohanty/

Research Interests: ultrafast nonlinear optics, nanophotonics, biopolymer multifunctional materials, material science, photonic crystals, photonic crystal fibers

Research Interests: electrolytes, gels, polymers, ion transport, energy storage

Research Interests: materials engineering, materials science, manufacturing processes, quality control

Research Interests: Physical Chemistry and Surface Science. The Shultz group applies physics and chemistry to understand the inner workings of hydrogen bonding. Hydrogen bonding plays key roles in environmental, biological, and atmospheric chemistry. Our program has research thrusts in all three directions. We specialize both in devising environments that clearly reveal key interactions and in developing new instrumentation. The most recent focus is on icy surfaces and on clathrate formation. Probing the ice surface begins with a well-prepared single-crystal surface. We have unique capabilities for growing single-crystal ice from the melt and for and preparing any desired ice face. Our clean water efforts are aimed at developing new materials to fill the significant need for safe drinking water. According to the World Health Organization, over one billion people lack safe drinking water. Our program is based on using photo catalysts to capture readily available sunlight to turn pollutants into benign CO2 and water. We developed methods to grow ultra-nano (~2 nm) particles that have well-controlled surface structures and chemistry.

Research Interests: Engineering for Health, Mechanics of biomaterials at the nanoscale, Synthesis and study of functionals nanomaterials for biomedical imaging and drug delivery, Advanced imaging for medical diagnostics, Novel processes and materials for dentistry: nano-polishing and self-healing materials

Research Interests: Flexible bioelectronics, Biomedical microdevices, Biomedical circuits and systems, micro and nano fabrication, lab-on-chip microsystems, global health and precision medicine, CMOS image sensors for scientific imaging, analog to information converters, active metamaterial devices, circuits, and systems, terahertz devices and circuits

Research Interests: Biological Physics, Condensed Matter Physics, Quantum Mechanics My research interests cover a broad array of topics in biological physics and condensed matter physics. In Biological Physics our group is performing both experimental and theoretical work to uncover fundamental physical principles that underlie the formation of functional neuronal networks among neurons in the brain. One of the primary challenges in science today is to figure out how as many as 100 billion neurons are produced, grow, and organize themselves into the truly wonderful information-processing machine which is the brain. We combine high-resolution imaging techniques such as atomic force microscopy, traction force and fluorescence microscopy to measure mechanical properties of neurons and to correlate these properties with internal components of the cell. Our group is also using mathematical modeling based on stochastic differential equations to predict axonal dynamics and network formation. The aim of this work is twofold. On the one hand we are using tools and concepts from experimental and theoretical physics to understand biological processes. On the other hand, active biological processes in neuronal cells exhibit a wealth of fascinating phenomena such as pattern formation, collective behavior, and non equilibrium dynamics, and thus the insights learned from studying these biological systems broaden the intellectual range of physics. To capture the complexity of neuronal interactions we use theoretical methods from statistical mechanics and many-body physics such as: stochastic differential equations, Fokker-Planck formalism, Markov processes, effective energy landscape etc. I am also interested in the foundations of quantum mechanics, particularly in applying the theory of stochastic processes to open quantum systems. My interests in condensed matter physics includes experimental work on quantum transport in nanoscale systems (carbon nanotubes, graphene, polymer composites, hybrid nanostructures), as well as on scanning probe microscopy and the study of novel biomaterials.

Research Interests: Physical Chemistry, Surface Science, and Nanoscience. The Sykes group utilizes state of the art scanning probes and surface science instrumentation to study technologically important systems. For example, scanning tunneling microscopy enables visualization of geometric and electronic properties of catalytically relevant metal alloy surfaces at the nanoscale. Using temperature programmed reaction studies of well defined model catalyst surfaces structure-property-activity relationships are drawn. Of particular interest is the addition of individual atoms of a reactive metal to a relatively inert host. In this way reactivity can be tuned, and provided the energetic landscapes are understood, novel bifunctional catalytic systems can be designed with unique properties that include low temperature activation and highly selective chemistry. Newly developed curved single crystal surface are also being used to open up previously inaccessible areas of structure sensitive surface chemistry and chiral surface geometries. In a different thrust, the group has developed various molecular motor systems that are enabling us to study many important fundamental aspects of molecular rotation and translation with unprecedented resolution.

Research Interests: Organic Materials Chemistry Our group applies the philosophy of physical organic chemistry to organic materials, in the forms of polymers, crystals and surfaces. Specifically, we investigate new materials that show macroscopic changes in properties upon exposure to external stimuli. Our main focus has been new materials that respond to light, which has a unique combination of characteristics: i) easy control over where light goes and when it goes there (spatiotemporal control), ii) easy control over intensity and energy, and iii) the ability to pass through many solid materials that traditional chemical reagents cannot. Our research has focused in three separate areas. 1. Photochemical control of charge. As interactions between charges dictate much of molecular behavior, controlling charge can yield control over matter. We have developed a series of materials in which light switches the charge-based interactions between polymer chains from attractive. By combining this top-down fabrication approach of with the bottom-up fabrication method of layer-by-layer assembly, we have developed thin films in which photochemical lability is confined to individual nanoscale compartments, yielding photo-delaminated free-standing films and multi-height photolithography. 2. Using functional side chains to control conjugated materials. Conjugated materials hold great promise for applications including solar cells and displays. We have focused on expanding the role of the side-chains of these materials, which occupy up to half of their mass but are typically reserved only for solubility. Early work in our group focused on integrating photolabile side chains for negative conjugated photoresists. This has evolved to using the non-covalent interactions of aromatic side-chains for controlling interactions between molecules, and therefore their material properties, including the use of mechanical force to control luminescence—mechanofluorochromism. 3. Singlet-oxygen responsive materials. Singlet oxygen (1O2) is a critical reactive oxygen species in photodynamic therapy for cancer as well as in damage to plants upon overexposure to light. Its photochemical production is also chemically amplified through a photochemical reaction, which is the lynchpin of several commercial bioanalytical technologies. Through a combination of fundamental physical organic chemistry and materials chemistry, we have luminescent conjugated polymer nanoparticles as probes for 1O2 in water that shows improved limit of detection over the commercially available luminescent probe for 1O2.

Research Interests: nanoelectronics, biosensing, biomaterials, tissue engineering, drug delivery

Research Interests: Experimental condensed matter physics; physics education My primary physics research is in experimental surface science. In my lab at 574 Boston Ave., my students and I study what happens when foreign atoms and molecules form chemical bonds with metal surfaces. We examine how the interaction between the foreign molecule and the metal modify properties of both of them. In recent years a particular focus has been on how the attachment of the foreign molecule changes the electrical resistivity of the metal substrate. This area of research has relevance to a range of potential applications including catalysis, chemical sensing, and the growth of thin films and nanoparticles on surfaces. A second area of activity is physics education, particularly at the elementary school level. Together with collaborators at a local nonprofit organization and at other universities, I am working to develop and study curriculum materials and professional development strategies for teachers to improve instruction in science in grades 3-5.

Research Interests: Physical and Surface Chemistry. The Utz group studies how molecules react on surfaces. Reactions at the gas-surface interface are highly dynamical events. Large-scale atomic and vibrational motions transform reactants into products on sub-ps and Å scales. The experiments probe ultrafast nuclear motion and energy flow dynamics that underlie heterogeneous catalysis and chemical vapor deposition. The goal is to to better model existing processes and direct the rational design of new catalytic materials and deposition techniques. The experiments use vibrational- and rotational-state selective laser excitation of molecules in a supersonic molecular beam to provide precise control over the energetics and orientation of the gas-phase reagent as it approaches the surface. Reaction probability and product identity is then quantified as a function of the reagent's energetic configuration. These experiments have shown that the vibrational state of the incident molecule can have a profound effect on reaction probability, and suggest that energy redisribution within the reaction complex is not complete prior to reaction and that the competing kinetics of energy redistribution and reaction might be manipulated to control the outcome of a reaction. This has been subsequently confirmed by exerting bond-elective control over a heterogeneously catalyzed reaction.

Research Interests: Microelectromechanical Systems (MEMS) fabrication, modeling, and testing. Particularly acoustic MEMS (microphones, ultrasound), and aerodynamic measurement technologies (skin friction sensors, aeroacoustic sensors). Acoustics, vibrations, dynamics and controls. Electromechanical systems including robotics. Finite element methods and system modeling. Electronics for measurement. Mechanical measurements.

Research Interests: biomaterials, drug delivery, micro/nanofabrication, tissue engineering

Research Interests: nanobiofabrication, smart biopolymers, BioMEMS, material science

Research Interests: novel polymer electrolytes for batteries, liquid crystal polymers, composite materials, materials science